Binuclear Guanidinate Yttrium Carbyne Complex: Unique Reactivity toward Unsaturated C<i>−</i>N, C<i>−</i>O and C<i>−</i>S Bonds
نویسندگان
چکیده
A guanidinato-stabilized binuclear yttrium carbyne complex [(PhCH 2 ) NC(NC 6 H 3 i Pr -2,6) ] Y (µ -Me)(AlMe 4 -CH) ( 1 was synthesized via C−H bond activation and its versatile reactivities were investigated. Complex underwent σ-bond metathesis with PhSSPh nucleophilic addition...
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ژورنال
عنوان ژورنال: Chemical Science
سال: 2023
ISSN: ['2041-6520', '2041-6539']
DOI: https://doi.org/10.1039/d3sc03483f